The triboelectric effect (also known as 'triboelectric charging') is a type of contact electrification in which certain materials become electrically charged after they come into contact with another different material and are then separated (such as through rubbing). The polarity and strength of the charges produced differ according to the materials, surface roughness, temperature, strain, and other properties.

Thus, it is not very predictable, and only broad generalizations can be made. Amber, for example, can acquire an electric charge by contact and separation (or friction) with a material like wool. This property, first recorded by Thales of Miletus, suggested the word "electricity", from the Greek word for amber, ēlektron. Other examples of materials that can acquire a significant charge when rubbed together include glass rubbed with silk, and hard rubber rubbed with fur.

Static electricity refers to the buildup of electric charge on the surface of objects. The static charges remain on an object until they either bleed off to ground or are quickly neutralized by a discharge. Although charge exchange can happen whenever any two surfaces come into contact and separate, a static charge will only remain when at least one of the surfaces has a high resistance to electrical flow (an electrical insulator). The effects of static electricity are familiar to most people because we can see, feel and even hear the spark as the excess charge is neutralized when brought close to a large electrical conductor (for example a path to ground), or a region with an excess charge of the opposite polarity (positive or negative). The familiar phenomenon of a static 'shock' is caused by the neutralization of charge.

When a relay is used to switch a large amount of electrical power through its contacts, it is designated by a special name: contactor. Contactors typically have multiple contacts, and those contacts are usually (but not always) normally-open, so that power to the load is shut off when the coil is de-energized. Perhaps the most common industrial use for contactors is the control of electric motors.